Effect of aniline and hydrazine derivatives on reversible oxygen addition in model systems of cobalt complexes of etioporphyrin and alpha, beta, gamma, delta-tetraphenylporphine
Ginzburg, S.F.; Ol'shanskaia, N.B.; Ponomarev, G.V.; Stanko, V.I.; Khrapov, V.V.
Biofizika 20(6): 987-990
1975
ISSN/ISBN: 0006-3029 PMID: 1203313 Document Number: 83520
The influence of aniline and hydrazine derivatives on the reversible oxygenation of cobaltous complexes of etioporphyrin I and alpha,beta,gamma,delta-tetraphenylporphin has been studied by means of ESR and electronic spectra. The formation of stable six-coordinated complexes with the said reagents prevents the oxygenation. The excess of hydrazines cause the destruction of porphyrin nucleus. The formation of intermediate dihydroporphyrins (chlorins) has been noticed.
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