Synthesis of N-acetylglucosamine beta-aryl glycosides catalyzed by crown ethers
Kur'ianov, V.O.; Chupakhina, T.A.; Zemliakov, A.E.; Kotliar, S.A.; Kamalov, G.L.; Chirva, V.I.
Bioorganicheskaia Khimiia 27(6): 434-438
2001
ISSN/ISBN: 0132-3423 PMID: 11811065 Document Number: 530939
Glycosylation of phenols of various structure with alpha-D-glucosaminyl chloride peracetate in a solid phase-liquid system catalyzed by crown compounds was studied. The highest yields of aryl beta-glycosides were observed at room temperature in acetonitrile using anhydrous potassium carbonate as a base. The optimum phenol-glycosyl donor-base-crown ether ratio was 1:1:1:0.2.
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