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The structure of eremomycin, a new antibiotic of the group of polycyclic glycopeptides

Lomakina, N.N.; Berdnikova, T.F.; Tokareva, N.L.; Abramova, E.A.; Dokshina, N.I.

Antibiotiki i Khimioterapiia 34(4): 254-258

1989

ISSN/ISBN: 0235-2990
PMID: 2751381
Document Number: 329453
Structure of the carbohydrate moiety of the eremomycin molecule was assessed. Two residues of eremosamine were detected in the antibiotic. One of them in the composition of 2-0-(L-eremosaminyl)-D-glucopyrazone dissaccharide was linked by the phenol group to monodechlorvancomycinic acid and the other formed the monosaccharide branch by the alcohol group of the same acid at the peptide C-end area. On the basis of the results of the present study and the data published earlier (structure of the aglycone and aminosugar) the structure of eremomycin was assigned.

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