Sesquiterpenes and an intermediate 1alpha, 6beta, 11-eudesmanetriol in the biosynthesis of geosmin from Streptomyces sp
Yang, Y.-B.; Yang, Z.; Yang, X.-Q.; Zhang, Y.; Zhao, L.-X.; Xu, L.-H.; Ding, Z.-T.
Yao Xue Xue Bao 47(3): 364-366
2012
ISSN/ISBN: 0513-4870 PMID: 22645760 Document Number: 659931
One new sesquiterpene was isolated from the fermentation broth of Streptomyces sp. and the structure was elucidated by spectral analysis as caryolane-1, 6beta-diol (1). An intermediate 1alpha, 6beta, 11-eudesmanetriol (2) in the biosynthesis of geosmin was also found in this strain which proved sequence for the reactions, especially bicyclization preceding dealkylation.
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