Acyl migration on nucleic acid compounds related to adenosine
Anzai, K.; Uzawa, J.
Nucleic Acids Symposium Series 16: 101-103
1985
ISSN/ISBN: 0261-3166 PMID: 4088850 Document Number: 252168
Treatment of N6,N6-di-p-toluyl-2',3'-O-isopropylideneadenosine (7) with ZnBr2 in 1,4-dioxane afforded a 8,5'-O-cycloadenosine derivative 8 exclusively. Reaction of 2',3'-O-isopropylideneadenosine (1) with p-cyanobenzoyl chloride in a CH2Cl2-Et3N mixture afforded a ring-cleaved compound 11 as the main product.
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