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Phosphorylated derivitaves of All-Z and 3-demethyl-tri-TRANS, di-cis- hexaprenols as substrates for O-antigen polysaccharide biosynthesis in Salmonella anatum

Kalinchuk, N.A.; Danilov, L.L.; Druzhinina, T.N.; Mal'tsev, S.D.; Shibaev, V.N.; Iudina, O.N.; Grigor'eva, N.I.; Moiseenkov, A.M.

Bioorganicheskaia Khimiia 17(2): 268-272

1991

ISSN/ISBN: 0132-3423
PMID: 1713765
Document Number: 371220
Phosphates of all-Z- and 3-demethyl-tri-trans, di-cis-hexaprenols have been prepared and studied as substrates for enzymes of the Salmonella anatum O-specific polysaccharide biosynthesis. Methyl group in alpha-isoprenic unit proved to be essential for the enzyme-substrate interaction, whereas the presence of E-isoprenic units near the omega-end of the polyprenol is not significant.

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